Serena Daolio has sung in concerts with Renato Bruson, Vincenzo La Scola, Daniela Barcellona and with orchestras including Sanremo Orchestra Sinfonica, Torre del Lago, Teatro Regio in Parma, Orchestra Sinfonica A. Toscanini, St John’s Hall in London for “The Rosenblatt Recital Series”. She has sung in Mozart's Kronungs Mass, Vivaldi's Gloria, Rossini's Petite Messe Solennelle, Fauré's Requiem, and in recital specialises in the music of French composers Duparc, Debussy and Ravel.
Among her roles in Italian opera houses have been Violetta in La Traviata, Lauretta in Gianni Schicchi, Mimì in La Boheme and the title role in Offenbach's La Belle Helene. She has sung under the baton of Riccardo Muti in Gluck's Iphgenie en Aulide at La Scala in Milan. In 2004 she sang the role of Gulnara in Il Corsaro by Giovanni Pacini under Bruno Bartoletti at Verdi Festival of Parma, Mimì in La Boheme produced by Luciano Pavarotti in Fano, and in 2005 she received rave reviews for her portrayal of Giulietta in Marchetti's Romeo e Giulietta at Martina Franca Festival, with recording for Dynamic.
She then sang the role of Anna in Nabucco at the Liceu, Barcelona, with Maria Guleghina, Leo Nucci and Aquiles Machado, conducted by Nello Santi. In 2006 she made her debut as Liu’ in Turandot at the Sferisterio of Macerata, production of Pier Luigi Pizzi, under Daniele Callegari. She was Musetta at Palau de les Arts Reina Sofia in Valencia under Xian Zhang, production of Pierre Audi.
In 2007 she was Nedda in Pagliacci at Teatro Real in Madrid under Jesus Lopez Cobos in a new production of Giancarlo Del Monaco, she made her debut as Micaela in Carmen in Fidenza and as Marcella by Giordano at the Festival Valle D’Itria in Martina Franca. She sang Micaela in the new production of Carmen at Maggio Musicale Fiorentino 2008 under Zubin Mehta and most recently, Liu in Turandot again with Zubin Mehta in Tel Aviv with the Israel Philharmonic Orchestra.